5.2.3 Radioactive Decay
Definition of Radioactivity
Radioactivity is a change in an unstable nucleus that can result in the emission of α (alpha) particles, β⁻ (beta) particles, and/or γ (gamma) radiation.
Key Characteristics
- Radioactive changes are spontaneous and random — they cannot be predicted or controlled.
- Isotopes may be radioactive due to:
- Excess neutrons in the nucleus, or
- A nucleus too heavy to remain stable.
- During α-decay or β-decay, the nucleus transforms into that of a different element.
- Decay increases nuclear stability by reducing excess neutrons and energy.
Change During Beta Emission
In β⁻ decay, a neutron changes into a proton and an electron.
neutron → proton + electron
Products of Nuclear Decay
A radioactive substance emits one or more of the following radiations during decay, often accompanied by the release of energy.
Alpha Decay (α)
- The nucleus loses two protons and two neutrons (an alpha particle).
- Mass number decreases by 4; atomic number decreases by 2.
- A new element is formed that is two places lower in the Periodic Table.
Example:
²³⁸₉₂U → ²³⁴₉₀Th + ⁴₂He
- Uranium-238 decays into thorium-234 and emits an alpha particle.
Beta Decay (β⁻)
- A neutron changes into a proton and emits an electron (beta particle).
- Mass number remains the same; atomic number increases by 1.
- The nucleus of the new atom has one more proton and one less neutron.
Example:
¹⁴₆C → ¹⁴₇N + ⁰₋₁e
- Carbon-14 decays into nitrogen-14 and emits a beta particle.
Gamma Decay (γ)
- Occurs after α or β decay, when the nucleus remains in an excited state with extra energy.
- The nucleus emits a gamma ray — a wave of high-frequency electromagnetic radiation.
- No change in atomic number or mass number.
- Gamma emission helps the nucleus lose excess energy and become more stable.
Example:
⁶⁰₂₇Co* → ⁶⁰₂₇Co + γ
- The excited nucleus of cobalt-60 emits a gamma ray and returns to a stable energy state.
Summary of Decay Effects
| Type of Decay | Change in Mass Number | Change in Atomic Number | Effect |
|---|---|---|---|
| Alpha (α) | −4 | −2 | New element formed, two places lower in Periodic Table |
| Beta (β⁻) | 0 | +1 | New element formed, one place higher in Periodic Table |
| Gamma (γ) | 0 | 0 | Nucleus loses excess energy; no change in composition |
| Application | Type of Radiation | Purpose |
|---|---|---|
| Smoke alarms | Alpha (α) | Detect smoke particles that interrupt the ionisation current. |
| Sterilising medical instruments | Gamma (γ) | Kill bacteria and microorganisms on equipment. |
| Food irradiation | Gamma (γ) | Kill bacteria and extend shelf life of food products. |
| Thickness control | Beta (β) | Used to maintain uniform thickness in paper or metal sheets. |
| Cancer treatment (radiotherapy) | Gamma (γ) | Kill cancer cells by focused radiation without surgery. |
| Cancer diagnosis | Gamma (γ) | Use radioactive tracers; gamma camera detects emissions from tumour areas. |
Explanation — Thickness Monitoring
- A beta emitter is placed on one side of a sheet and a detector on the opposite side.
- If the sheet becomes thicker → fewer beta particles pass through → detected activity decreases.
- This signals the rollers to reduce pressure to maintain correct thickness.
- Beta radiation is ideal because it can penetrate paper or thin aluminium, but not thick metal.
Explanation — Cancer Treatment and Diagnosis
- Gamma rays have high penetrating power and can destroy living cells.
- In radiotherapy, focused gamma beams kill cancer cells without surgery.
- In diagnosis, radioactive tracers injected into the body emit gamma rays that are detected using a gamma camera.
- Cancerous cells absorb more tracer due to their higher metabolic rate, forming a brighter image.
Mark Scheme Highlights
- Always correct for background radiation before analysing decay data.
- State that half-life is constant and unaffected by external factors.
- For gamma rays, note they are high-frequency electromagnetic waves with high energy and short wavelength.
- Lead sheets reduce gamma count rate but do not completely absorb it.
- Half-life can be determined graphically by finding time for count rate to halve.
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