IGCSE Physics Notes

Examination Year: 2025–2027
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igcse Thermal physics

Cambridge IGCSE Physics
Syllabus: 2025–2027

States of Matter

All matter exists in three main forms: solids, liquids, and gases. The differences arise from how their particles are arranged and how they move.

Molecular Structure

  • Solids — particles are closely packed and vibrate about fixed positions.
  • Liquids — particles are close together but can slide over each other.
  • Gases — particles are far apart and move randomly in all directions.

Distinguishing Properties

Comparison of flow, shape, volume and density for solids, liquids and gases.
Property Solid Liquid Gas
Flow No Yes Yes
Shape Fixed Takes container shape Fills container
Volume Fixed Fixed Can be changed
Density High High Low

Change of State

Matter can change from one state to another by heating or cooling.

Process Summary
  • Melting: Solid → Liquid
  • Boiling / Evaporation: Liquid → Gas
  • Condensation: Gas → Liquid
  • Freezing: Liquid → Solid
Exam Note

For the 2023–2025 examinations, sublimation (solid ↔ gas) is not required.

Key Formula

For perpendicular vectors (analogy for resultants): R = √(X² + Y²)

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The Particle Model

The particle model explains the properties of solids, liquids, and gases in terms of the arrangement, separation, and motion of their particles.

Comparison of Solids, Liquids and Gases

Property Solids Liquids Gases
Arrangement Particles arranged in a fixed, regular pattern. Particles not arranged in any fixed pattern. Particles arranged randomly.
Separation Particles very close together. Particles close together. Particles far apart.
Motion Particles vibrate about fixed positions. Particles slide past each other. Particles move freely and rapidly.
Summary by State
  • Solid: Molecules form a 3D lattice; vibrate about fixed positions. When heated, they gain kinetic energy and may melt or sublime.
  • Liquid: Molecules stay in contact but move freely; forces of attraction are weaker than in solids, allowing flow but maintaining volume.
  • Gas: Forces between molecules are negligible; particles move freely and collide with each other and container walls, producing gas pressure.

Temperature and Motion of Particles

Temperature indicates how hot or cold a substance is and is related to the average kinetic energy of its particles.

Key Relationship

As temperature increases → particle motion increases.
As temperature decreases → motion decreases.
At absolute zero (0 K) → particles cease all motion.

Temperature Scales
  • Celsius scale: 0 °C = melting point of ice, 100 °C = boiling point of water.
  • Fahrenheit scale: 32 °F = melting point, 212 °F = boiling point.
  • Kelvin scale: 273 K = freezing point, 373 K = boiling point.

T(K) = T(°C) + 273

Absolute zero = 0 K or −273 °C → particles have minimum kinetic energy.

Gas Pressure and Particle Collisions

  • Gas pressure results from collisions between gas particles and container walls.
  • Each collision exerts a force on the wall.
  • Increasing the number of particles or their temperature increases collision frequency → higher pressure.

Brownian Motion

Brownian motion is the random, zig-zag motion of microscopic particles suspended in a fluid, caused by collisions with fast-moving molecules of the fluid.

Evidence for the Kinetic Model

Observed by Robert Brown using pollen grains in water.
It provides direct evidence that particles of matter are in constant motion.

Exam Tip

When describing Brownian motion, distinguish between the microscopic particles (visible under a microscope) and the molecules of the fluid causing the collisions.

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Gases and the Absolute Scale of Temperature

The behavior of gases can be described by relationships between pressure, volume, and temperature. These are known as the gas laws.

1. Pressure Law (Temperature–Pressure Relationship)

Statement

For a fixed mass of gas at constant volume:
P ∝ T or P₁ / T₁ = P₂ / T₂

Increasing temperature gives gas particles more kinetic energy. They move faster, colliding more frequently and forcefully with the walls of the container, increasing pressure. Lowering temperature reduces molecular motion and hence lowers the pressure.

Summary of Effect (Constant Volume)
  • ↑ Temperature → ↑ Molecular speed → ↑ Pressure
  • ↓ Temperature → ↓ Molecular speed → ↓ Pressure

2. Boyle’s Law (Pressure–Volume Relationship)

Statement

For a fixed mass of gas at constant temperature:
P ∝ 1/V or P × V = constant

Explanation

Reducing the volume of a gas pushes particles closer together, increasing the rate of collisions with the container walls. This increases pressure. Doubling the volume halves the pressure, and vice versa.

Worked Example

P₁V₁ = P₂V₂
If P₁ = 2 × 10⁵ Pa, V₁ = 0.35 m³, and P₂ = 5 × 10⁵ Pa:
V₂ = (P₁ × V₁) / P₂ = 0.14 m³.

3. The Absolute (Kelvin) Temperature Scale

Temperature is a measure of the average kinetic energy of particles. Raising temperature increases motion; lowering temperature reduces it. At absolute zero (0 K), particle motion ceases completely.

Scale Freezing Point of Water Boiling Point of Water Conversion
Celsius (°C) 0 °C 100 °C T (K) = T (°C) + 273
Fahrenheit (°F) 32 °F 212 °F
Kelvin (K) 273 K 373 K
Exam Tip

Always convert temperatures to Kelvin when applying gas laws. 0 K (−273 °C) is the lowest attainable temperature where particle kinetic energy is minimum.

4. Pressure Explained by Molecular Motion

  • Gas pressure is due to collisions of particles with container walls.
  • Each collision exerts a force on the wall.
  • More particles or higher temperature → more frequent collisions → higher pressure.
  • Pressure = Force / Area.

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Thermal Expansion of Solids, Liquids and Gases

Thermal expansion is the increase in size (length, area or volume) of a body due to a change in temperature, usually when it is heated.

Qualitative Description at Constant Pressure

State of Matter Observation Explanation
Solids Expand slightly when heated at constant pressure. Strong bonds hold particles tightly; only small vibrations are possible, requiring heat energy for mechanical work.
Liquids Temperature increases steadily until boiling point is reached; then no further rise occurs. Weaker bonds than solids allow particles to slide past each other and occupy a larger volume when heated.
Gases Expand greatly when heated under constant pressure. Particles move freely; heating increases their kinetic energy, causing harder collisions and expansion (as in a gas syringe).

Relative Magnitude of Expansion

State Relative Expansion Reason
Solid Least Particles held by very strong forces of attraction; intermolecular spaces are very small, allowing only vibration.
Liquid Moderate Particles held by weaker forces of attraction; can slide past each other, so volume increases moderately on heating.
Gas Largest Forces of attraction negligible; particles move freely and spread out widely when heated, producing the greatest expansion.

Everyday Applications of Thermal Expansion

Examples
  • Metal washer fitting: Engineers heat a metal washer before fitting it on a steel rod. Heating causes expansion, allowing it to fit; on cooling, it contracts tightly.
  • Overhead wires sag: On hot days, wires expand and sag; on cold days, they contract and become taut.
  • Iron tyre on a wheel: Heating expands the iron ring so it can be placed on the wooden wheel. Cooling makes it contract, gripping the wheel firmly.
Key Idea

Thermal expansion occurs in all states of matter but to different extents:
Solids < Liquids < Gases
Expansion depends on the strength of intermolecular forces and available space between particles.

Exam Tip

When comparing expansion, always state both extent and reason. Example: “Liquids expand more than solids because their particles are further apart and forces are weaker.”

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Specific Heat Capacity

The specific heat capacity (c) of a substance is the energy required per unit mass per unit temperature increase .

Definition & Formula

c = E / [ m × (θ₂ − θ₁) ]

or   E = m c (θ₂ − θ₁)

Units: J kg⁻¹ °C⁻¹

Experimental Determination (Aluminium Block Method)

Measurements Required
  • Mass of aluminium block (m)
  • Initial temperature (θ₁) and final temperature (θ₂)
  • Voltage (V), Current (I) and Time (t) for which heat is supplied
Energy Supplied

Electrical energy is given by E = V × I × t.

Therefore, c = (V × I × t) / [m × (θ₂ − θ₁)]

Sources of Error & Precautions

Heat Loss and Corrections
  • If the block is not insulated, heat escapes to the environment → temperature rise smaller → c appears larger.
  • Use lagging or insulation around the block to reduce heat losses.
  • Polish or paint the surface white to reduce radiation loss.
  • Place a lid on the block to prevent convection currents.
  • Reduce draughts in the room.
Typical Values & Observation

Water has a very high specific heat capacity:

  • Takes a long time to heat up and to cool down.
  • Requires large amount of energy → expensive for heating.
  • Helps stabilise climate and body temperature in living organisms.

Summary Table

Quantity Symbol Typical Unit Formula
Energy transferred E joule (J) E = m c Δθ
Mass m kilogram (kg)
Specific heat capacity c J kg⁻¹ °C⁻¹
Temperature change Δθ °C (or K)
Alternative Form

c = ΔE / (m Δθ)

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Melting, Boiling and Evaporation

The change of state of matter can be explained using the kinetic particle theory. Heat energy changes the motion and spacing of particles, leading to melting, boiling or evaporation.

Heating Curve Explanation (Kinetic Theory)

Stages of Heating a Solid
  • A–B: Temperature of the solid rises as particles vibrate faster with increased kinetic energy.
  • B–C: Temperature remains constant while particles overcome forces of attraction — the solid melts.
  • C–D: Temperature rises again as liquid particles gain more kinetic energy.
  • D–E: Temperature remains constant; energy breaks remaining forces between particles — the liquid boils.
  • E–F: Gas particles move freely, far apart, with rapidly increasing kinetic energy.
Equilibrium During Melting

Solid ⇌ Liquid (X(l))

Key Notes
  • A pure substance shows sharp melting (B–C) and boiling (D–E) points.
  • An impure substance melts at a lower and boils at a higher temperature range.

Comparison: Particles in Liquid vs Gas

Stage Separation between Particles Movement of Particles Can Fill Container?
C–D (Liquid) Close and touching Random and slow Cannot move apart completely
E–F (Gas) Far apart Fast and random Yes, fills entire container

Evaporation

Evaporation is the process in which surface molecules of a liquid gain enough kinetic energy to escape into the air as vapour.

Explanation
  • Only molecules with the highest kinetic energy escape from the surface.
  • Energy is used to overcome intermolecular attraction, not to raise temperature.
  • Hence, the liquid cools down after evaporation — evaporation causes cooling.

Factors Affecting Rate of Evaporation

  • Temperature (higher → faster evaporation)
  • Surface area (larger → faster evaporation)
  • Draught or airflow (removes vapour, increasing rate)

Everyday Uses of Evaporation

  • Making salt in salt pans by evaporating seawater.
  • Drying clothes faster on a hot or windy day.
  • Cooling of tea and perspiration from skin.

Difference Between Evaporation and Boiling

No. Evaporation Boiling
1 Occurs only at the surface of the liquid. Occurs throughout the liquid.
2 Can occur at any temperature. Occurs only at the boiling point.
3 Causes cooling as high-energy particles escape. Does not cause cooling; temperature remains constant.
4 No bubbling observed. Vigorous bubbling occurs.
Key Idea

During melting or boiling, temperature stays constant while latent heat is absorbed to break forces between particles. Kinetic energy does not increase until the phase change is complete.

Exam Tip

Remember: In both melting and boiling, energy is used to overcome forces of attraction — not to increase temperature. Cooling by evaporation relies on faster molecules escaping first.

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Conduction

Conduction is the process of heat transfer through a material from a region of higher temperature to a region of lower temperature, without any overall movement of the substance.

Conduction in Metals

  • Metals contain free (mobile) electrons that move through the metal lattice.
  • When heated at one end, these electrons gain kinetic energy and move faster.
  • They collide with other electrons and positive ions in cooler regions, transferring energy.
  • Additionally, metal ions vibrate more vigorously and pass on their vibrations to neighbouring ions.
  • Thus, heat is transferred efficiently from the hot end to the cold end through both free electrons and ion vibrations.

Conduction in Non-Metallic Solids

  • Non-metals do not have free electrons.
  • Heat is transferred only by vibration of atoms within the lattice.
  • This process is much slower and less efficient than in metals.
  • Hence, non-metals are poor conductors (thermal insulators).

Facts about Conduction

  • Conduction cannot occur in a vacuum.
  • Metals conduct heat better than non-metals.
  • Conduction can occur in solids, liquids, and gases — but least efficiently in gases.

Why Gases Conduct Heat Poorly

Gases have very few molecules, spaced far apart. Energy transfer occurs only by collisions and diffusion during random molecular motion. Hence, conduction in gases is very weak.

Experimental Demonstration — Comparing Conductivity

Equal heat is applied to several metal rods with wax rings fixed along their length. The rod that loses the wax rings fastest is the best conductor of heat.

Observation

The metal that conducts heat fastest will have fewest wax rings left after a fixed time. This experiment demonstrates comparative thermal conductivity.

Comparison: Good Conductors vs Insulators

Property Good Conductors (e.g. Metals) Insulators (e.g. Wood, Plastic)
Free Electrons Present and mobile Absent
Heat Transfer Mechanism By free electrons and ion vibrations By vibration of atoms only
Speed of Heat Transfer Fast Slow
Thermal Conductivity High Low
Examples Copper, Aluminium, Silver Wood, Glass, Air
Key Idea

In solids, heat transfer by conduction is due to two processes:
• Electron movement (dominant in metals)
• Atomic vibration (dominant in non-metals)

Exam Tip

Conduction cannot occur in a vacuum — there are no particles to transfer energy. Remember: Metals → good conductors, Non-metals → poor conductors.

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Convection

Convection is the transfer of heat in liquids and gases through the movement of the fluid itself.

Key Features
  • Occurs only in liquids and gases.
  • Heat is transferred by circulating currents within the fluid.
  • Hotter, less dense regions rise; cooler, denser regions sink, creating a convection current.

Explanation in Terms of Density Changes

When a fluid is heated, its particles move faster and spread apart, causing the fluid to expand. Because the mass remains the same, the density decreases, making the warmer region rise upward. Cooler, denser fluid then sinks to take its place, establishing a continuous cycle.

Summary Process
  • Heated fluid expands → less dense → rises upward.
  • Cooler fluid sinks to replace it → more dense.
  • This creates a continuous convection current.
Convection Currents

Convection currents efficiently transfer thermal energy from hotter to cooler parts of a fluid. This is why stirring is not required when heating liquids; heat spreads naturally by convection.

Examples of Convection in Daily Life

1. Sea Breeze (Daytime)

During the day, the land heats up faster than the sea. The air above the land becomes hot and less dense, so it rises. Cooler air from above the sea moves in to take its place, forming a sea breeze — air moving from sea to land.

2. Land Breeze (Nighttime)

At night, the land cools faster than the sea. The air above the warmer sea becomes hotter and less dense, so it rises. Cooler air from the land moves out to take its place, forming a land breeze — air moving from land to sea.

Situation Hot Region Direction of Air Movement Breeze Name
Daytime Land hotter than sea From sea to land Sea breeze
Nighttime Sea hotter than land From land to sea Land breeze
Exam Tip

In convection, heat transfer occurs because the particles move. This is different from conduction, where particles only vibrate.

Key Points to Remember
  • Convection cannot occur in solids or in a vacuum.
  • Heating a fluid from below produces stable convection currents.
  • Applications: room heaters, sea and land breezes, boiling water.

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Radiation

Thermal radiation is the transfer of heat energy by electromagnetic waves — mainly infra-red radiation. Unlike conduction or convection, it does not require a medium for transfer.

Key Features
  • Occurs through infra-red radiation.
  • Can take place even in a vacuum.
  • All objects emit and absorb infra-red radiation.
  • Hotter objects emit more radiation per second.

Special Cases

Rate of Emission vs Absorption
  • If emission rate > absorption rate → object cools down.
  • If emission rate = absorption rate → temperature remains constant.
  • If emission rate < absorption rate → object warms up.

Infrared Radiation

  • Part of the electromagnetic spectrum.
  • Every object emits infra-red radiation — hotter objects emit more.
  • Very hot objects also emit visible light along with IR radiation.
  • Infra-red radiation travels at the speed of light and does not need particles.
Experiment — Detecting Infrared Radiation

When a glass prism splits white light into a spectrum, a thermometer placed just beyond the red end shows a temperature rise. This invisible region is infra-red radiation, having a lower frequency than red light.

Effect of Surface Colour and Texture

Surface Type Absorption Emission Reflection
Dark, Dull, Matt Surface Good absorber Good emitter Poor reflector
Light, Shiny Surface Poor absorber Poor emitter Good reflector
Demonstration — Absorbers and Emitters

Two beakers are painted differently — one shiny silver, the other dull black. Both are filled with equal hot water. The black beaker cools faster, proving it is a better emitter and absorber of infra-red radiation.

Controlling Heat Absorption and Emission

  • In hot countries, houses are painted white to reflect more radiation.
  • White blinds or shutters reduce radiation absorption.
  • Thick walls prevent excessive conduction of heat inside buildings.
Applications — Thermos Flask
  • Silvered surfaces reflect heat radiation.
  • Vacuum layer prevents conduction and convection.
  • Plastic stopper acts as an insulator to reduce conduction.

Factors Affecting Emission Rate

  • Surface temperature — higher temperature → greater emission.
  • Surface area — larger area → faster radiation.
  • Colour and texture — dark and dull → better emitters.

Earth’s Temperature and Radiation Balance

Daytime
  • Earth’s surface absorbs large amounts of solar radiation.
  • Temperature rises as absorbed radiation exceeds emission.
  • Clear skies increase warming as less energy is reflected.
Night-time
  • More radiation is emitted than absorbed → temperature falls.
  • Clear nights cause rapid cooling (no clouds to reflect radiation back).
  • Cloudy nights stay warmer as clouds reflect infrared radiation back to Earth.

Overall, this balance maintains a fairly constant temperature on Earth, allowing life to survive.

Exam Tip

Radiation differs from conduction and convection because no particles or medium are required. The efficiency of absorption and emission depends strongly on surface colour, texture, and area.

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Consequences of Thermal Energy Transfer

The transfer of thermal energy has several important everyday applications. These applications make use of one or more modes of heat transfer — conduction, convection, and radiation.

Example 1 — Heating of a Pan

Explanation
  • The base of the metal pan is heated by a flame.
  • Conduction transfers heat from the flame through the metal base.
  • The water inside the pan is heated by convection currents.
  • The hot water rises and the cooler water sinks, ensuring even heating throughout.
Energy Pathway

Flame → Metal base (conduction) → Water (convection) → Surroundings (radiation)

Exam Tip

Metal handles get hot due to conduction. Insulated handles prevent burns.

Example 2 — Heating a Room by Convection

Explanation
  • Heaters are placed near the floor since warm air rises.
  • As air near the heater warms up, it expands and becomes less dense.
  • The warm air rises, and cooler, denser air moves in to take its place.
  • This sets up a convection current that circulates warm air throughout the room.
Key Idea

Convection ensures uniform temperature in the room — warm air moves upward, cool air descends.

Example 3 — Fire Burning Coal

Explanation
  • Heat from the fire spreads in three ways:
  • Radiation: Infra-red rays heat nearby objects and people directly.
  • Convection: Hot air rises, carrying heat upwards and warming surroundings.
  • Conduction: The metal grate and nearby surfaces conduct heat from the fire.
Combined Heat Transfer

Coal fire → Radiation (to people) + Convection (to air) + Conduction (to metal parts)

Example 4 — Radiator in a Car

Explanation
  • Hot water from the engine flows through thin metal tubes of the radiator.
  • Conduction transfers heat from the hot water to the metal walls.
  • Convection carries the heat away through the moving air around the tubes.
  • Radiation helps transfer some heat directly to the surroundings.
  • This prevents the engine from overheating.
Summary of Modes
Application Conduction Convection Radiation
Heating a Pan Metal base conducts heat Water circulates heat Surface emits radiation
Room Heating Walls conduct slightly Warm air circulates Heater radiates warmth
Coal Fire Metal parts conduct heat Hot air rises Infra-red radiated out
Car Radiator Metal tubes conduct Air carries heat away Radiation helps cooling
Exam Tip

Real-life heating often involves all three methods of heat transfer. Identify which is most dominant in each example.

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Thermal Physics — Key Terms Enrichment

Master these foundation terms to decode questions quickly. Hover/tap the highlighted terms for quick meanings, and use the examples to anchor ideas to real situations. :contentReference[oaicite:0]{index=0}

Quick Meanings & One-line Hooks

Term Student-friendly meaning One-line example (IGCSE-style)
Endothermic Takes in energy (usually heat) from the surroundings. Ice melting absorbs energy → beaker feels colder.
Exothermic Gives out energy to the surroundings. Water freezing releases energy → keeps liquid at 0 °C until solidified.
Temperature Indicator of average kinetic energy of particles (°C or K). At higher T, gas particles collide more → pressure rises at fixed volume.
Intermolecular bonds Attractive forces between particles; must be overcome to melt/boil. At boiling point, energy breaks attractions instead of raising T.
Kinetic energy Energy due to particle motion; increases as T increases. Heating a gas → faster particles → more frequent/forceful wall hits.
Infra-red radiation EM waves (IR) that transfer heat; works even in vacuum. Sun warms Earth via IR; black, matt surfaces absorb/emit best.
Endothermic vs Exothermic — at a glance
  • Endothermic: energy IN to break intermolecular bonds (melting, boiling, sublimation).
  • Exothermic: energy OUT as bonds form/strengthen (freezing, condensation, deposition).

Energy in → (break bonds) → state change to less ordered
Energy out → (form bonds) → state change to more ordered

Temperature, Kinetic Energy & Bonding (Particle View)

  • Raising temperature → increases average kinetic energy → particles move faster.
  • At a flat part of a heating curve (melting/boiling), energy is used to overcome intermolecular bonds, so temperature stays constant.
  • Cooling curves: the reverse — energy released as bonds form (exothermic plateaus).

Infra-red Radiation — Surfaces Matter

  • Black/dull → better absorber & emitter of IR.
  • White/shiny → poorer absorber & emitter; better reflector.
  • No medium needed → IR works through a vacuum (space).
Exam Tips
  • Use K (Kelvin) for gas-law calculations; convert by T(K)=T(°C)+273.
  • On plateaus, write: “Temperature constant because energy changes bonding, not kinetic energy.”
  • Always state the direction of energy flow (into system vs out to surroundings) when saying endo/exo.

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